Oxidative desulfurization of thiophene on TiO2/ZSM-12 zeolite
نویسندگان
چکیده
منابع مشابه
A Systematic Study on the Effect of Desilication of Clinoptilolite Zeolite on its Deep-Desulfurization Characteristics
Natural clinoptilolite zeolite (CLP) in its original or metal ion- exchanged form (Ni2+) is a weak adsorbent for relatively large thiophene derivative molecules like benzothiophene (BT) and di-benzothiophene (DBT), due to its rather restricted micro-channel structure. A novelty of this work is that upon desilication treatments, it is possible to enhance the adsorption behavior of Ni2+-exchanged...
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Kinetic and isotopic methods were used to probe elementary steps and site requirements for thiophene hydrogenation and desulfurization on Ru metal clusters. Turnover rates for these reactions were unaffected by whether samples were treated in H2 or H2S to form metal and sulfide clusters, respectively, before reaction. These data, taken together with the rate and extent of sulfur removal from us...
متن کاملa systematic study on the effect of desilication of clinoptilolite zeolite on its deep-desulfurization characteristics
natural clinoptilolite zeolite (clp) in its original or metal ion- exchanged form (ni2+) is a weak adsorbent for relatively large thiophene derivative molecules like benzothiophene (bt) and di-benzothiophene (dbt), due to its rather restricted micro-channel structure. a novelty of this work is that upon desilication treatments, it is possible to enhance the adsorption behavior of ni2+-exchanged...
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The adsorption and desorption of thiophene and the reactions of thiophene-derived adsorbed species in He, H2, and O2 were examined on H-ZSM5, H-Beta, and H-Y with varying Si/Al ratios. Thiophene adsorption uptakes (per Al) were independent of Al content, but were above unity and influenced by zeolite structure (1.7, 2.2, and 2.9 on H-ZSM5, H-Beta, and H-Y). These data indicate that thiophene ol...
متن کاملAn Experimental Study on the Operating Parameters of Ultrasound-assisted Oxidative Desulfurization
In this research, the effects of important parameters, including the molar ratio of acetic acid to sulfur(S) , sonication time, temperature, and hydrogen the molar ratio of peroxide to sulfur on the performance of ultrasound-assisted oxidative desulfurization were studied using the response surface method (RSM). To this end, a model fuel containing n-decane and dibenzothiophene at a concentrati...
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ژورنال
عنوان ژورنال: Materials Research
سال: 2016
ISSN: 1980-5373,1516-1439
DOI: 10.1590/1980-5373-mr-2015-0130